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61.
Levels of total mercury (T-Hg) were surveyed in red meat (n=73) and liver (n=3) from toothed whales, dolphins and porpoises (odontocetes) sold for human consumption in the coastal cities of South Korea. High concentrations of T-Hg were found in the liver products of finless porpoises (18.7 and 156 microg/wet g) and common dolphins (13.2 microg/wet g). The T-Hg concentrations in red meat products were highest in the false killer whale (9.66+/-12.3 microg/wet g, n=9), bottlenose dolphin (10.6+/-12.6 microg/wet g, n=3) and killer whale (13.3 microg/wet g, n=1), and lowest in Cuvier's beaked whale and the harbour porpoise (0.4-0.5 microg/wet g). Thus, most of the products that originated from odontocetes exceeded the safety limit of 0.5 microg/wet g for T-Hg set by the South Korean health authorities for the fishery industry. Pregnant women and other vulnerable sectors of the population living in South Korea should therefore limit their consumption of odontocete products.  相似文献   
62.
Based on almost all available published age data, the protolith ages, peak metamorphic ages and cooling rate of the Sambagawa metamorphic belt have been discussed and the latest constraints on the ages of the Sambagawa metamorphism and subduction-related accretionary evolutions were summarized. Peak metamorphic conditions attained within the Kuma nappe complex at ca. 145-185 Ma, and uplift through ca. 500℃at ca. 150 Ma and 350-400癈 at ca. 110 -115 Ma. The protolith sediments of the Besshi nappe complex were accumulated and subsequently progressively subducted and suffered high P-T prograde metamorphism during the Kuma nappe complex uplifting. The Besshi nappe complex arrived maximum metamorphic conditions at ca. 110- 120 Ma and subsequently started rapid uplift with the cooling rate of ca. 14.2℃/Ma at ca. 75 -85 Ma, followed with the cooling rate of ca. 6.0-8.9℃/Ma. The Oboke nappe complex started subduction later than other tectonic units and arrived the peak metamorphic conditions at ca. 75 Ma, which followed by the uplift with a cooling rate of ca. 8℃/Ma.  相似文献   
63.
Continental recycling and true continental growth   总被引:1,自引:0,他引:1  
Continental crust is very important for evolution of life because most bioessential elements are supplied from continent to ocean. In addition, the distribution of continent affects climate because continents have much higher albedo than ocean, equivalent to cloud. Conventional views suggest that continental crust is gradually growing through the geologic time and that most continental crust was formed in the Phanerozoic and late Proterozoic. However, the thermal evolution of the Earth implies that much amounts of continental crust should be formed in the early Earth. This is “Continental crust paradox”.Continental crust comprises granitoid, accretionary complex, and sedimentary and metamorphic rocks. The latter three components originate from erosion of continental crust because the accretionary and metamorphic complexes mainly consist of clastic materials. Granitoid has two components: a juvenile component through slab-melting and a recycling component by remelting of continental materials. Namely, only the juvenile component contributes to net continental growth. The remains originate from recycling of continental crust. Continental recycling has three components: intracrustal recycling, crustal reworking, and crust–mantle recycling, respectively. The estimate of continental growth is highly varied. Thermal history implied the rapid growth in the early Earth, whereas the present distribution of continental crust suggests the slow growth. The former regards continental recycling as important whereas the latter regarded as insignificant, suggesting that the variation of estimate for the continental growth is due to involvement of continental recycling.We estimated erosion rate of continental crust and calculated secular changes of continental formation and destruction to fit four conditions: present distribution of continental crust (no continental recycling), geochronology of zircons (intracontinental recycling), Hf isotope ratios of zircons (crustal reworking) and secular change of mantle temperature. The calculation suggests some important insights. (1) The distribution of continental crust around at 2.7 Ga is equivalent to the modern amounts. (2) Especially, the distribution of continental crust from 2.7 to 1.6 Ga was much larger than at present, and the sizes of the total continental crust around 2.4, 1.7, and 0.8 Ga became maximum. The distribution of continental crust has been decreasing since then. More amounts of continental crust were formed at higher mantle temperatures at 2.7, 1.9, and 0.9 Ga, and more amounts were destructed after then. As a result, the mantle overturns led to both the abrupt continental formation and destruction, and extinguished older continental crust. The timing of large distribution of continental crust apparently corresponds to the timing of icehouse periods in Precambrian.  相似文献   
64.
Abstract— Phosphates in martian meteorites are important carriers of trace elements, although, they are volumetrically minor minerals. PO4 also has potential as a biomarker for life on Mars. Here, we report measurements of the U‐Th‐Pb systematics of phosphates in the martian meteorite ALH 84001 using the Sensitive High Resolution Ion MicroProbe (SHRIMP) installed at Hiroshima University, Japan. Eleven analyses of whitlockites and 1 analysis of apatite resulted in a total Pb/U isochron age of 4018 ± 81 Ma in the 238U/206Pb‐207Pb/206Pb‐204Pb/206 Pb 3‐D space, and a 232Th‐208Pb age of 3971 ± 860 Ma. These ages are consistent within a 95% confidence limit. This result is in agreement with the previously published Ar‐Ar shock age of 4.0 ± 0.1 Ga from maskelynite and other results of 3.8–4.3 Ga but are significantly different from the Sm‐Nd age of 4.50 ± 0.13 Ga based on the whole rock and pyroxene. Taking into account recent studies on textural and chemical evidence of phosphate, our result suggests that the shock metamorphic event defines the phosphate formation age of 4018 ± 81 Ma, and that since then, ALH 84001 has not experienced a long duration thermal metamorphism, which would reset the U‐Pb system in phosphates.  相似文献   
65.
Much research has been conducted for physics‐based ground‐motion simulation to reproduce seismic response of soil and structures precisely and to mitigate damages caused by earthquakes. We aimed at enabling physics‐based ground‐motion simulations of complex three‐dimensional (3D) models with multiple materials, such as a digital twin (high‐fidelity 3D model of the physical world that is constructed in cyberspace). To perform one case of such simulation requires high computational cost and it is necessary to perform a number of simulations for the estimation of parameters or consideration of the uncertainty of underground soil structure data. To overcome this problem, we proposed a fast simulation method using graphics processing unit computing that enables a simulation with small computational resources. We developed a finite‐element‐based method for large‐scale 3D seismic response analysis with small programming effort and high maintainability by using OpenACC, a directive‐based parallel programming model. A lower precision variable format was introduced to achieve further speeding up of the simulation. For an example usage of the developed method, we applied the developed method to soil liquefaction analysis and conducted two sets of simulations that compared the effect of countermeasures against soil liquefaction: grid‐form ground improvement to strengthen the earthquake resistance of existing houses and replacement of liquefiable backfill soil of river wharves for seismic reinforcement of the wharf structure. The developed method accelerates the simulation and enables us to quantitatively estimate the effect of countermeasures using the high‐fidelity 3D soil‐structure models on a small cluster of computers.  相似文献   
66.
Recently, energy service providers (ESP) have increased due to deregulation in the power market. They install energy supply equipment at their own cost and supply the necessary energy to the client. The Tokyo Metropolitan Government started Asia’s first cap-and-trade program in April 2010. This program caps energy-related carbon dioxide emissions from some 1,330 offices and factories in Tokyo. Then, ESPs have to manage the many risks of energy service project directly linked to the profits. In this paper, we describes the risk analysis and investment optimization for energy service projects using financial engineering.  相似文献   
67.
The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl and HCO3 remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO3 concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO3 /Cl ratio of 305 differed markedly from downcore pore water HCO3 /Cl ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ18O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ18O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ18O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.  相似文献   
68.
Coupled hillslope and channel processes in headwater streams (HWS) lead to rapid changes in channel dimensions. Changes in channel size and shape caused by a debris flow event along the length of a headwater stream in the Ashio Mountains, Japan, were captured with the aid of repeat high-definition surveys using terrestrial laser scanning (TLS) techniques. The HWS was classified into three distinct reaches below the debris flow initiation zone. A large knickpoint separated an upper bedrock reach from a colluvial reach along the midsection of the drainage. The colluvial reach transitioned to a lower bedrock reach that terminated at the master stream. Cross-sectional and morphometric analyses revealed no statistically significant changes in channel size or shape along the upper bedrock reach. Debris flow erosion generated significant differences in channel size and shape along a colluvial reach. Sediment bulking associated with erosion along the colluvial reach led to increases in channel size along the lower bedrock reach, but no statistical differences in channel shape. Morphometric analyses from the TLS point cloud revealed that debris flow erosion produced a distinct nonlinear change in channel dimensions in the downstream direction within the HWS. Variations in channel substrate along the length of HWS contributed directly to this nonlinear response. The episodic nature and nonlinearity of erosion associated with the current debris flow event highlights the importance of debris flows in general in understanding the transport of sediment, coarse to fine particulate organic material, and large woody debris, which are critical to the long-term management of riverine environments. TLS sampling methods show promise as one component of a multianalytical approach needed to continuously monitor and manage the dynamics of HWS.  相似文献   
69.
We produced a four-dimensional variational ocean re-analysis for the Western North Pacific over 30 years (FORA-WNP30). It is the first-ever dataset covering the western North Pacific over 3 decades at eddy-resolving resolution. The four-dimensional variational analysis scheme version of the Meteorological Research Institute Multivariate Ocean Variational Estimation system (MOVE-4DVAR) is employed to conduct a long-term reanalysis experiment during 1982–2012. After evaluating the basic performance of FORA-WNP30, the interannual to decadal variability is analyzed. Overall, FORA-WNP30 reproduces basic features in the western North Pacific well. One of outstanding features in FORA-WNP30 is that anomalous events such as the Kuroshio large meander and anomalous intrusion of the Oyashio in the 1980s, when there were no altimeter data, are successfully reproduced. FORA-WNP30 is therefore a valuable dataset for a variety of oceanographic research topics and potentially for related fields such as climate study, meteorology and fisheries.  相似文献   
70.
Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials.  相似文献   
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